1620144-03-7Relevant articles and documents
Selective Kumada biaryl cross-coupling reaction enabled by an iron(iii) alkoxide-N-heterocyclic carbene catalyst system
Chua, Yi-Yuan,Duong, Hung A.
, p. 8424 - 8427 (2014/07/22)
A catalyst system comprising Fe2(OtBu)6 and an N-heterocyclic carbene ligand enables efficient syntheses of (hetero)biaryls from the reactions of aryl Grignard reagents with a diverse spectrum of (hetero)aryl chlorides. Amongst the alkoxide and amide counterions investigated, tert-butoxide was the most effective in inhibiting the homocoupling of arylmagnesiums. This journal is the Partner Organisations 2014.