1620157-90-5Relevant academic research and scientific papers
AgOTf/I2-Mediated Cyclization/Cross-Coupling/Isomerization of Enynones with Phosphorus Ylides: An Expedient Route to Stereoselective Synthesis of (E)-2-Alkenylfurans
Deng, Guisheng,Tang, Ling,Zhang, Yangyi
, p. 13245 - 13251 (2021/10/01)
Ag(I)-catalyzed cascade reactions involving enynone cyclization and cross-coupling with phosphorus ylides have been achieved for the first time. Subsequent treatment of the reaction mixture with I2 afforded the corresponding (E)-α-alkenylfurans in 73-95%
Zinc-catalyzed synthesis of 2-alkenylfurans via cross-coupling of enynones and diazo compounds
González, Jesús,López, Luis A.,Vicente, Rubén
supporting information, p. 8536 - 8538 (2014/07/22)
Inexpensive, less-toxic ZnCl2 serves as the catalyst for selective cross-coupling of enynones and diazo compounds, an unprecedented reaction pathway for zinc carbenoids. A cascade sequence comprising formal cyclization/cross-coupling leads to a variety of 2-alkenylfurans. the Partner Organisations 2014.
