1620403-36-2Relevant academic research and scientific papers
Rhodium(iii)-catalyzed intramolecular amidoarylation and hydroarylation of alkyne via C-H activation: Switchable synthesis of 3,4-fused tricyclic indoles and chromans
Zhang, Xue,Li, Yifei,Shi, Hui,Zhang, Lunan,Zhang, Shanshan,Xu, Xianxiu,Liu, Qun
supporting information, p. 7306 - 7309 (2014/07/07)
The controllable intramolecular amidoarylation and hydroarylation of alkynes has been achieved via rhodium(iii)-catalyzed C-H activation. The merger of two distinct reaction pathways allows for the development of atom- and step-economic protocols for the
Rh(III)-catalyzed intramolecular redox-neutral or oxidative cyclization of alkynes: Short, efficient synthesis of 3,4-fused indole skeletons
Zhou, Bing,Yang, Yaxi,Tang, Huanyu,Du, Juanjuan,Feng, Huijin,Li, Yuanchao
, p. 3900 - 3903 (2014/08/18)
A Rh(III)-catalyzed intramolecular redox-neutral or oxidative annulation of a tethered alkyne has been developed to efficiently construct 3,4-fused indoles via a C-H activation pathway. The advantages of this process are (1) ready availability of annulation precursors; (2) broad substrate scope; (3) complete regioselectivity; (4) simple and mild reaction conditions; and (5) no need for an external oxidant or to employ molecular oxygen as the stoichiometric terminal oxidant.
