1620461-83-7

Basic information

• Product Name: C₂₆H₃₆ClN₂NiP
• Synonyms: C₂₆H₃₆ClN₂NiP
• CAS NO: 1620461-83-7
• Molecular Weight: 501.702
• Mol File: 1620461-83-7.mol

Chemical Properties

• CAS DataBase Reference: C₂₆H₃₆ClN₂NiP(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₃₆ClN₂NiP(1620461-83-7)
• EPA Substance Registry System: C₂₆H₃₆ClN₂NiP(1620461-83-7)

Safety Data

• Hazardous Substances Data: 1620461-83-7(Hazardous Substances Data)

Upstream product

• 29046-78-4 (1,2-dimethoxyethane)dichloronickel(II) 
• 1620461-85-9 2-(dicyclohexylphosphinophenyl)-2-(dimethylaminophenyl)amine 

Relevant articles and documents

P,N,N-Pincer nickel-catalyzed cross-coupling of aryl fluorides and chlorides

P,N,N-Pincer nickel complexes [Ni(Cl){N(2-R2PC6H 4)(2′-Me2NC6H4)}] (R = Ph, 3a; R = Pri, 3b; R = Cy, 3c) were synthesized and their catalysis toward the Kumada or Negishi cross-coupling reaction of aryl fluorides and chlorides was evaluated. Complex 3a effectively catalyzes the cross-coupling of (hetero)aryl fluorides with aryl Grignard reagents at room temperature. Complex 3a also catalyzes the cross-coupling of (hetero)aryl chlorides and arylzinc reagents at 80 °C with low catalyst loadings and good functional group compatibility. the Partner Organisations 2014.