162060-48-2

Upstream product

• 162060-47-1 phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-seleno-β-D-galactopyranoside 
• 68779-52-2 1,2-O-(1-methoxyethylidene)-3,4,6-tri-O-benzyl-α-D-galactopyranose 
• 80040-79-5 3,4,6-tri-O-benzyl-D-galactal 
• 645-96-5 Benzeneselenol 

Downstream Products

• 162060-52-8 ((2S,3R,4S,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-phenylselanyl-tetrahydro-pyran-3-yloxy)-((2S,4S,5R,6S)-4,5-bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-ylmethoxy)-dimethyl-silane 
• 208983-37-3 Acetic acid (2S,3R,4S,5R,6R)-3-((2S,3S,4S,5S,6R)-3-acetoxy-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-5-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yl ester 
• 208983-36-2 C₄₉H₅₆O₁₀ 

Relevant academic research and scientific papers

Stereoselective synthesis of β-Phenylselenoglycosides from glycals and rationalization of the selenoglycosylation processes

β-Phenylselenoglycosides have been efficiently and stereoselectively synthesized by direct oxidative glycosylation of benzenselenolate (PhSe -) with glycals. A rationalization of the presently described β-selectivity and the opposite α-selectivity reported by Danishefsky in the ring-opening of epoxy glycals with benzeneselenol (PhSeH) is proposed.

The Use Of Selenophenyl Galactopyranosides for the Synthesis of α- and β-(1->4)-C-Disaccharides

Methyl α-C-lactoside 4)-α-D-Glcp-OMe> and its α anomer were expeditiously synthesized by radical coupling of various selenophenyl galactopyranosides onto methyl 2,3-di-O-benzyl-4-deoxy-4-C-methylene-α-D-xylo-hexopyranoside, which are tempor