1620642-91-2Relevant academic research and scientific papers
Yttrium-catalysed dehydrocoupling of alanes with amines
Nako, Adi E.,Gates, Sarah J.,Sch?del, Nicole,White, Andrew J. P.,Crimmin, Mark R.
supporting information, p. 9536 - 9538 (2014/08/18)
We report [Y{N(SiMe3)2}3] as a precatalyst for the dehydrocoupling of sterically demanding amines with β-diketiminate stabilised aluminium dihydrides. While simple fluorinated anilines readily undergo Al-H/N-H dehydrocoupling under thermal conditions, catalytic methods are required to achieve reasonable rates of reaction for ortho-substituted anilines or hindered aliphatic amines. This journal is the Partner Organisations 2014.
