1620682-47-4

Basic information

• Product Name: cinnamyl 3-methyl-2-nitrobenzoate
• Synonyms: cinnamyl 3-methyl-2-nitrobenzoate
• CAS NO: 1620682-47-4
• Molecular Weight: 297.31
• Mol File: 1620682-47-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cinnamyl 3-methyl-2-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: cinnamyl 3-methyl-2-nitrobenzoate(1620682-47-4)
• EPA Substance Registry System: cinnamyl 3-methyl-2-nitrobenzoate(1620682-47-4)

Safety Data

• Hazardous Substances Data: 1620682-47-4(Hazardous Substances Data)

Upstream product

• 5437-38-7 3-methyl-2-nitrobenzoic acid 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Downstream Products

• 1620682-61-2 1-((E)-3-(3-methyl-2-nitrophenyl)prop-1-enyl)benzene 

Relevant articles and documents

Palladium(0)-catalyzed intramolecular decarboxylative allylation of ortho nitrobenzoic esters

A Pd/Ag bimetallic system has been developed for the decarboxylative allylation of ortho-nitrobenzoic esters in an intramolecular fashion. In contrast to the typical sp2-sp3 cross-coupling approach which requires air and moisture sensitive preformed organometallic reagents, we provide an alternative route to the synthesis of ortho-allyl nitroarenes from the corresponding ortho-nitrobenzoic acid derivatives. The reaction proceeds through a mechanistically distinct decarboxylative metalation pathway. A cooperative reactivity of palladium and silver is crucial for the reaction outcome.