1621087-92-0Relevant academic research and scientific papers
Rhodium(III)-catalyzed regioselective C-H alkenylation of phenylphosphine sulfides
Yokoyama, Yuki,Unoh, Yuto,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
, p. 7649 - 7655 (2014/09/16)
The regioselective alkenylation at the ortho position of phenylphosphine sulfides using alkenes proceeds efficiently in the presence of a cationic Cp*-rhodium(III) catalyst and an appropriate oxidant. A similar rhodium catalyst also promotes the redox-neutral coupling of the phosphine sulfides with alkynes to afford ortho-alkenylated products.
