1621092-34-9Relevant academic research and scientific papers
Gold(I)-catalyzed synthesis of optically active 1,4-oxazepan-7-ones
Kamimura, Akio,Yamane, Yu,Yo, Ryuichiro,Tanaka, Toshiyuki,Uno, Hidemitsu
, p. 7696 - 7702 (2014)
Optically active seven-membered lactones, dimethyleneoxazepanones, were readily prepared in good yields from chiral β-(N-propargylic)amino-α- methylene carboxylic acid tert-butyl esters in the presence of catalytic amounts of Ph3PAuCl and Cu(OTf)2. A smooth 7-exo-dig cyclization was observed.
