1621189-46-5Relevant academic research and scientific papers
Synthesis and characterization of new chiral azolinium salts, precursors to N-heterocyclic carbenes, derived from l-proline
Thomasset, Amélia,Bouchardy, Lucie,Bournaud, Chloée,Guillot, Régis,Toffano, Martial,Vo-Thanh, Giang
, p. 242 - 250 (2014/03/21)
A short and flexible procedure for the preparation of seven chiral azolinium and five functionalized chiral azolinium salts, precursors to N-heterocyclic carbenes, derived from l-proline has been developed. Moderate to good overall yields were obtained. Some NHC dimers and thiones were isolated. X-ray crystal structure determinations of two [Rh-NHC] complexes were also reported.
