1621487-07-7Relevant academic research and scientific papers
Silver-catalyzed formal insertion of arynes into Rf-I bonds
Zeng, Yuwen,Hu, Jinbo
supporting information, p. 6866 - 6870 (2014/06/09)
An unprecedented silver-catalyzed formal insertion of arynes into R f-I (Rf=CF3, C2F5) bonds has been developed. This protocol provides easy access to various ortho-perfluoroalkyl iodoarenes under mild conditions. In this insertion reaction, an ionic atom-transfer reaction of RfI occurs, and a silver-mediated metathesis process is involved in the efficient transfer of the electropositive iodine atom.
