162157-05-3 Usage
General Description
[(4S)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]-Ferrocene, also known as DPMOF, is a chemical compound that consists of a ferrocene core linked to a 2-oxazoline ring substituted with a phenylmethyl group. It is a chiral molecule with a 4S configuration. DPMOF has been studied for its potential applications in asymmetric catalysis and as a chiral ligand in organometallic chemistry. The ferrocene core provides stability and redox properties, while the chiral 2-oxazoline ring allows for selective interactions with other molecules or catalysts. [(4S)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]-Ferrocene is of interest due to its unique structural and electronic properties and its potential for use in enantioselective reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 162157-05-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,2,1,5 and 7 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 162157-05:
(8*1)+(7*6)+(6*2)+(5*1)+(4*5)+(3*7)+(2*0)+(1*5)=113
113 % 10 = 3
So 162157-05-3 is a valid CAS Registry Number.
162157-05-3Relevant articles and documents
Bis(perfluoroalkyl) phosphino-oxazoline: A modular, stable, strongly π-accepting ligand for asymmetric catalysis
Hu, Zongjian,Li, Yuguang,Liu, Kai,Shen, Qilong
, p. 7957 - 7967 (2013/01/15)
A new class of stable, strongly π-accepting and modular bis-(perfluoroalkyl)-phosphine-oxazoline ligands (FOX) as CO mimics was prepared. It was demonstrated that these ligands, when coordinated to palladium catalysts, promote the asymmetric alkylation of monosubstituted allyl substrates with excellent regio- and enantioselectivity. Solid and solution structure analysis of the FOX-ligated Pd-allyl intermediate reveals that the combination of relative steric and strong trans influences presented by the P(CF 3)2 moiety gave rise to the excellent selectivity.
