1621957-56-9

Basic information

• Product Name: 5-(fluorosulfonyl)-2-methyl-1,3-dinitrobenzene
• Synonyms: 5-(fluorosulfonyl)-2-methyl-1,3-dinitrobenzene
• CAS NO: 1621957-56-9
• Molecular Weight: 264.191
• Mol File: 1621957-56-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-(fluorosulfonyl)-2-methyl-1,3-dinitrobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(fluorosulfonyl)-2-methyl-1,3-dinitrobenzene(1621957-56-9)
• EPA Substance Registry System: 5-(fluorosulfonyl)-2-methyl-1,3-dinitrobenzene(1621957-56-9)

Safety Data

• Hazardous Substances Data: 1621957-56-9(Hazardous Substances Data)

Upstream product

• 1211580-68-5 1-methyl-2-nitro-4-(pentafluorosulfanyl)benzene 
• 203126-21-0 pentafluoro(p-tolyl)-λ⁶-sulfane 

Relevant articles and documents

Synthesis of 4-(pentafluorosulfanyl)benzenediazonium tetrafluoroborate and analogs and their application for the preparation of SF5-aromatics

4-(pentafluorosulfanyl)benzenediazonium tetrafluoroborate salt was synthesized and isolated. The pentafluorosulfanyl salt was examined in a wide assortment of reactions to form novel SF5-bearing alkenes, alkynes, and biaryl derivatives using Heck-Matsuda, Sonogashira, and Suzuki coupling protocols. Dediazoniation of the salt furnished the corresponding p-SF5—C6H4X,C6H4OS(O)(CF3)═NSO2CF3, and p-SF5—C6H4-NTf2 derivatives. The azide derivative p-SF5—C6H4N3 entered into click chemistry with phenylacetylenes to furnish the corresponding triazoles. Various SF5-bearing alkenes were synthesized by coupling reactions using a metal catalyst. Fluorodediazoniation selectively furnished the fluoro derivative p-SF5—C6H4F. Homolytic dediazoniation gave the unsymmetrical biaryls, thus demonstrating the broad utility of pentafluorosulfanyl diazonium salts as building blocks of SF5-aromatics that are in high demand in many branches of chemistry including biomedicine and materials chemistry.