162222-05-1

Basic information

• Product Name: t-butyl 3-oxo-2-phenylbutanoate
• Synonyms: t-butyl 3-oxo-2-phenylbutanoate
• CAS NO: 162222-05-1
• Molecular Weight: 234.295
• Mol File: 162222-05-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: t-butyl 3-oxo-2-phenylbutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl 3-oxo-2-phenylbutanoate(162222-05-1)
• EPA Substance Registry System: t-butyl 3-oxo-2-phenylbutanoate(162222-05-1)

Safety Data

• Hazardous Substances Data: 162222-05-1(Hazardous Substances Data)

Upstream product

• 1694-31-1 tert-butyl acetoacetate 

Downstream Products

• 72410-67-4 tert-butyl 2-diazo-2-phenylacetate 
• 1426657-66-0 tert-butyl 2-(3-oxocyclohex-1-enyl)-2-phenylacetate 
• 1426658-03-8 tert-butyl 2-(3-oxocyclopent-1-enyl)-2-phenylacetate 
• 1432601-51-8 (S)-tert-butyl 2-(3-oxocyclohex-1-enyl)-2-phenylacetate 

Relevant articles and documents

Asymmetric Synthesis of α-Chloro-α-halo Ketones by Decarboxylative Chlorination of α-Halo-β-ketocarboxylic Acids

Chiral α-chloro-α-fluoro ketones were synthesized by enantio-selective decarboxylative chlorination of α-chloro-β-ketocarboxylic acids in the presence of a chiral amine catalyst. The reaction yielded the corresponding α-chloro-α-fluoro ketones with modera

Catalytic enantioselective carbon insertion into the β-vinyl C-H bond of cyclic enones

Chiral oxazaborolidinium ion-catalyzed Csp2-H functionalization of enones using diazoacetate has been developed. Various β-substituted cyclic enones were synthesized in high yield (up to 99%) with high to excellent enantioselectivity (up to 99%