162232-02-2Relevant academic research and scientific papers
Tris(diphenylphosphino)methanide Gold(III) Complexes. Crystal Structures of > and AuCl>
Fernandez, Eduardo J.,Gimeno, M. Concepcion,Jones, Peter G.,Ahrens, Birte,Laguna, Antonio,et al.
, p. 3487 - 3492 (1994)
The reaction of (acac = acetylacetonate) with (Ph2P)3CH led to > 1, which reacts further with (X = Cl or C6F5, tht = tetrahydrothiophene), ClO4 or AgClO4 to give dinuclear AuX> or trinuclear complexes >2M> (M = Au or Ag).Complex 1 reacted with gold(III) complexes to give dinuclear Au(C6F5)2X> (X = Cl or C6F5) or trinuclear complexes >2Au(C6F5)2>.Complex 1 is protonated by reaction with HBF4.The structures of complex 1 and AuCl> have been established by X-ray crystallography, confirming in the latter that the gold(I) centre is co-ordinated to the free phosphorus instead of the methanide C.
