162291-59-0

Upstream product

• 69546-72-1 carbonylchlorohydridobis(methyldi-t-butylphosphine)ruthenium(II) 
• 591-51-5 phenyllithium 

Downstream Products

• 162340-65-0 Ru[P(C(CH₃)3)2(CH₃)]2(CO)(C₆H₅)Cl 
• 192719-76-9 RuH(C₆H₄CH₃)(CO)2(CH₃P(C(CH₃)3)2)2 
• 192719-75-8 RuH(C₆H₄CH₃)(CO)2(CH₃P(C(CH₃)3)2)2 
• 183555-69-3 Ru(CO)3(P((t)Bu)2Me)2 
• 162340-64-9 RuH(C₆H₅)(CO)2(CH₃P(C(CH₃)3)2)2 
• 155150-40-6 RuH(SiH(C₆H₅)2)(CO)(P(C(CH₃)3)2CH₃)2 
• 878750-76-6 RuH(2-C₆FH₄)(CO)(p(t-Bu)2Me)2 

Relevant academic research and scientific papers

Intramolecular Hydrogen Site Exchange in an HRu(SiHPh2) Moiety

RuH(Ph)(CO)L2 (L = PBu2Me) reacts with SiH2Ph2 to give first benzene and RuH(SiHPh2)(CO)L2 and then RuH3(SiHPh2)(CO)L2 and Ru(H)2(CO)L2, the trihydride being formed by a dehydrogenative silane coupling reaction when excess SiH2Ph2 is present. Variable-temperature spin saturation transfer experiments reveal exchange between Ha and Hb in RuHa(SiHbPh2)(CO)L2; this occurs both by an intramolecular mechanism and (when SiH2Ph2 is present) by a mechanism dependent on SiH2Ph2 concentration. Spin saturation transfer also reveals exchange between all three of the above complexes via addition/loss of SiH2Ph2 or H2.