1623106-09-1

Basic information

• Product Name: C₂₆H₂₆As₂
• Synonyms: C₂₆H₂₆As₂
• CAS NO: 1623106-09-1
• Molecular Weight: 488.336
• Mol File: 1623106-09-1.mol

Chemical Properties

• CAS DataBase Reference: C₂₆H₂₆As₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₂₆As₂(1623106-09-1)
• EPA Substance Registry System: C₂₆H₂₆As₂(1623106-09-1)

Safety Data

• Hazardous Substances Data: 1623106-09-1(Hazardous Substances Data)

Relevant articles and documents

Asymmetric synthesis of a chiral diarsine ligand via a cycloaddition reaction between 3,4-dimethyl-1-phenylarsole and diphenylvinylarsine

The organopalladium complex containing ortho-metallated (S)-[1-(dimethylamino)ethyl]naphthalene as a chiral auxiliary has been successfully employed to promote the asymmetric cycloaddition reaction between 3,4-dimethyl-1-phenylarsole and diphenylvinylarsine. In the intramolecular cycloaddition reaction, a pair of separable diastereomeric palladium complexes was obtained in the ratio of 6:1. The chiral naphthylamine auxiliary could be removed chemoselectively from the template by treatment with HCl and subsequently NaI to generate the neutral diiodo complex [(As-As)PdI 2]. Treatment of the diiodo complex with KCN gave the enantiomerically pure As-As bidentate ligand in quantitative yield. In contrast to the reported similar P-P and As-P analogues, both arsenic donors in the diiodo complex could be readily eliminated to produce a structurally novel dimetallic complex.