162332-12-9Relevant academic research and scientific papers
Synthesis of 1,2-Cyclopropanated Sugars from Glycals
Murali, R.,Ramana, C. V.,Nagarajan, M.
, p. 217 - 218 (1995)
Syntheses of both forms of cyclopropanated sugars from glycals by (i) Simmons-Smith reaction and (ii) dichlorocarbene addition followed by dehalogenation are described.
Synthesis and Reactions of 1,2-Cyclopropanated Sugars
Ramana,Murali,Nagarajan
, p. 7694 - 7703 (2007/10/03)
Diastereospecific cyclopropanation of glycals 1, 2, 3, 4, and 41 was carried out using either dihalocarbene addition or zinc-carbenoid addition to yield 1,2-cyclopropanated sugars. Dichloroand dibromocarbenes added stereoselectively anti to the C3/s
