162333-05-3Relevant articles and documents
Chemical synthesis of β-homonojirimycin, of its N-butyl derivative, and of 'methyl homoazacellobioside'
Saavedra,Martin
, p. 6987 - 6993 (2007/10/03)
β-Homonojirimycin (2) was prepared by the highly stereoselective double reductive amination of a 2,6-heptodiulose derivative (6 or 13) using ammonium formate and NaBH3CN. The process was unsuccessful with primary amines. The synthesis of N-buty
Concise chemical synthesis of β-homonojirimycin and related compounds
Martin, Olivier R.,Saavedra, Oscar M.
, p. 799 - 802 (2007/10/02)
β-Homonojirimycin 2 was prepared in 27% overall yield from tetra-O-benzyl-D-glucono-1,5-lactone by way of the double reductive amination of a 2,6-heptodiulose (7). This synthetic approach provided also access to the 1,N-anhydro derivative of 2, compound 3