162365-61-9Relevant academic research and scientific papers
Nitrones in organic synthesis. Synthesis of secondary allyl amines
Dondoni,Merchan,Merino,Tejero
, p. 2551 - 2555 (1994)
Nitrones 1 undergo addition of vinyl organomagnesium bromide to give the allyl hydroxylamines 3 which are easily reduced to the corresponding N-benzyl allyl amines 2.
Formaldehyde as Tethering Organocatalyst: Highly Diastereoselective Hydroaminations of Allylic Amines
Hesp, Colin R.,MacDonald, Melissa J.,Zahedi, M. Mehdi,Bilodeau, Didier A.,Zhao, Shu-Bin,Pesant, Marc,Beauchemin, André M.
supporting information, p. 5136 - 5139 (2015/11/03)
Catalysts possessing sufficient activity to achieve intermolecular alkene hydroaminations under mild conditions are rare, and this likely accounts for the scarcity of asymmetric variants of this reaction. Herein, highly diastereoselective hydroaminations
