1623736-59-3

Basic information

• Product Name: (R)-tert-butyldiphenyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butoxy)silane
• Synonyms: (R)-tert-butyldiphenyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butoxy)silane
• CAS NO: 1623736-59-3
• Molecular Weight: 438.49
• Mol File: 1623736-59-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-tert-butyldiphenyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butoxy)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-tert-butyldiphenyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butoxy)silane(1623736-59-3)
• EPA Substance Registry System: (R)-tert-butyldiphenyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butoxy)silane(1623736-59-3)

Safety Data

• Hazardous Substances Data: 1623736-59-3(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 73183-34-3 bis(pinacol)diborane 
• 1006696-12-3 (R)-ethyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate 

Downstream Products

• 1623736-68-4 (7R,8R,11R,15R,19R)-2,2,7,11,15,19,23,23-Octamethyl-3,3,22,22-tetraphenyl-15-((triethylsilyl)oxy)-4,21-dioxa-3,22-disilatetracosan-8-ol 
• 1623736-74-2 (3R,7R,11R,15R)-1,16-bis-(tert-butyl-diphenyl-silanyloxy)-3,7,11,15-tetramethyl-11-triethylsilanyloxy-hexadecan-4-one 

Relevant articles and documents

Short stereoselective synthesis of the phytophthora universal mating hormone α1 using lithiation/borylation reactions

The universal mating hormone α 1 of the virulent plant pathogen Phytophthora has been synthesized in 12 steps and 28 % overall yield. Key CC bond-forming steps involved the use of two lithiation/borylation reactions to couple together enantioenriched building blocks, one of which also set up the stereochemistry of the tertiary alcohol at C11. Detailed analysis showed that the diastereomeric purity of the target molecule was >91 %, the highest obtained to date. In search of a mate: The universal mating hormone α 1 of the virulent plant pathogen Phytophthora has been synthesized in 12?steps and 28 % overall yield. Key CC bond-forming steps involved the use of two lithiation/borylation reactions to couple together enantioenriched building blocks, one of which also set up the stereochemistry of the tertiary alcohol at C11. The diastereomeric purity of the target molecule is >91 %, the highest obtained to date.