16247-01-1Relevant articles and documents
A convenient synthesis of primary 2-hydroxyorganophosphines from red phosphorus and oxiranes
Arbuzova,Brandsma,Gusarova,Van Der Kerk,Van Hooijdonk,Trofimov
, p. 65 - 66 (2007/10/03)
A number of 2-hydroxyorganophosphines HOCH(R1)CH(R2)PH2 2 have been obtained in good yields by reaction of oxiranes with sodium monophosphide, generated in situ from red phosphorus, sodium and tert-butyl alcohol in liquid
New ?2λ3-P=C-O Systems: Stable Non-Conjugated Phosphaalkene Ethers - Synthesis and Reactivity
Heinicke, Joachim,Kovacs, Ilona,Nyulaszi, Laszlo
, p. 493 - 496 (2007/10/02)
Non-conjugated cyclic phosphaalkene ethers (2, 4, 6) are obtained by cyclocondensation of (2- or 3-hydroxyalkyl)phosphanes 1,3 with N-arylpivalimidoyl chlorides.Hydrolysis of 2,4 with H2O (--> 7, 8), addition of hydrogen compounds (HCl, HSPh, MePhPH) (-->