16250-89-8Relevant academic research and scientific papers
Kinetics and mechanism of mercury(II)-catalyzed cyclization of N-phenyl-2-vinyloxyethanamine
Kukharev,Stankevich,Klimenko,Shainyan,Kukhareva
, p. 22 - 25 (2009)
The kinetic and thermodynamic parameters of the Hg(II)-catalyzed cyclization of N-phenyl-2-vinyloxyethanamine indicated that the first reaction step is reversible coordination of mercury at the vinyloxy group, followed by closure of mercurated oxazolidine
The synthesis of new 1,3-oxazolidines and 1,3-oxazinanes containing (η6-arene)tricarbonylchromium group based on condensation between aldehydes and amino alcohols
Artemov,Sazonova,Krylova,Zvereva,Pechen,Fukin,Cherkasov,Faerman,Grishina, N. Yu.
, p. 884 - 892 (2018/08/28)
The condensation reactions of β- and γ-amino alcohols containing phenyl or (η6-arene) tricarbonylchromium substituent with formaldehyde, acetaldehyde, benzaldehyde, and (η6-benzaldehyde)tricarbonylchromium were studied. The resulting 1,3-oxazolidine and 1,3-oxazinane products were isolated in a pure form and identified by different physicochemical methods. The effect of (η6-arene)tricarbonylchromium moiety on the reaction process was demonstrated.
One-Pot Synthesis of Ethyl 3-(2-Hydroxyalkyl)aminoalkanoates by Ring Opening of 1,3-Oxazolidines Using Reformatsky Reagent
Nishiyama, Tomihiro,Kishi, Hiroshi,Kitano, Kouji,Yamada, Fukiko
, p. 1765 - 1768 (2007/10/02)
Oxazolidines, obtained by the condensation of aldehydes with 2-anilino-1-alkanols, react with the Refortmatsky reagent derived from ethyl bromoacetate under mild reaction conditions to afford ethyl 3-(2-hydroxyalkyl)aminoalkanoates.
OXAZOLIDINES. 2. SYNTHESIS OF 2-METHYLOXAZOLIDINES BY CYCLIZATION OF VINYL ETHERS OF 1,2-AMINO ALCOHOLS
Kukharev, B.F.,Stankevich, V.K.,Klimenko, G.R.,Terent'eva, V.P.,Kukhareva, V.A.
, p. 440 - 442 (2007/10/02)
A study has been made of the catalytic activity of a number of proton acids and Lewis acids, amongst which mercury salts were particularly active, in the cyclization of N-phenylethanolamine vinyl ether to 2-methyl-3-phenyloxazolidine.A method for the preparative synthesis of 2-methyloxazolidines has been developed.
