162633-46-7Relevant articles and documents
Emission enhancement of a coplanar π-conjugated gelator without any auxiliary substituents
Xue, Pengchong,Yao, Boqi,Sun, Jiabao,Zhang, Zhenqi,Lu, Ran
, p. 10284 - 10286 (2014)
A linear coplanar carbazole-based benzoxazole derivative without any auxiliary moieties could gelatinize organic solvents, and exhibited emission enhancement owing to the J-aggregate formation. This journal is the Partner Organisations 2014.
The photooxidative sensitization of bis(: P-substituted diphenyl)iodonium salts in the radical polymerization of acrylates
Balcerak, Alicja,Kabatc, Janina
, p. 28490 - 28499 (2019)
The ability of two-component dyeing photoinitiating systems for the radical polymerization of 1,6-hexanediol diacrylate (HDDA) and 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate (TMPTA) is presented. The systems under study comprised a hemicyanine dye as a sensitizer and iodonium salts that played a role of a coinitiator. The kinetic parameters of the polymerization reaction, such as the rate of polymerization (Rp) and the degree of conversion of monomer (C%), were estimated. The thermodynamic feasibility of an electron transfer process in the systems studied was verified and calculated using the Rehm-Weller equation. It was found that a benzoxazole derivative in the presence of iodonium salts effectively initiated the polymerization of acrylate monomers. The polymerization rates of about 10-7 s-1 and the degree of conversion of acrylate groups from 20% to 50% were observed. The effects of photoinitiator structures on the initiating ability and spectroscopic properties of sensitizers are described in this article.
KF-Al2O3 catalyzed the condensations of 2-methylbenzoxazole and pyrazol-5-one with aromatic aldehydes
Sun,Yan,Han
, p. 151 - 154 (2007/10/03)
In the presence of KF-Al2O3 as a solid base, 2-methylbenzoxazole 1 in DMF and 1-phenyl-3-methylpyrazol-5-one 2 in methanol, respectively, reacted with aromatic aldehydes to give 2-styrylbenzoxazoles 4a-f in high yields and 1-phenyl-3