162707-70-2Relevant academic research and scientific papers
Tris(2,6-dimethoxyphenyl)borane and its adducts
Wada, Masanori,Kanzaki, Mitsuyuki,Ogura, Hideo,Hayase, Shuichi,Erabi, Tatsuo
, p. 127 - 134 (2007/10/02)
Tris(2,6-dimethoxyphenyl)borane, Φ3B (Φ = 2,6-(MeO)2C6H3), an air-stable crystalline compound, formed isolable 1:1 adducts with ammonia and some primary amines but not with tertiary amines, secondary amines, or sec-alkylamines.Some tetraalkylammonium tris(2,6-dimethoxyphenyl)cyanoborates are soluble both in water and in benzene, and the stearyltrimethylammonium salt is soluble even in n-hexane.The freezing point depression measurements for some tetraalkylammonium salts suggested that they are associated in benzene by several molecules.Keywords: Boron; 2,6-dimethoxyphenyl; Borate; Amine; Phosphonium; Solubility
