162808-27-7Relevant academic research and scientific papers
The 1H NMR method for the determination of the absolute configuration of 1,2,3-prim,sec,sec-triols
Lallana, Enrique,Freire, Felix,Seco, Jose Manuel,Quinoa, Emilio,Riguera, Ricardo
, p. 4449 - 4452 (2007/10/03)
The absolute configuration of 1,2,3-prim,sec,sec-triols can be assigned by comparison of the 1H NMR spectra of the tris-(R)- and the tris-(S)-MPA ester derivatives. An experimental demonstration of this correlation with 24 triols of known absolute configuration and a protocol using two parameters-ΔδRS(H3) and the difference between ΔδRS(H2) and ΔδRS(H3) = |Δ(ΔδRS)|-for its application to the determination of the absolute configuration of other triols are presented.
[(Z)-γ-[(diisopropylidene-α-D-mannopyranosyl)oxy]allyl]- tributylstannane: A new chiral reagent for the asymmetric α-hydroxyallylation of aldehydes
Roush, William R.,VanNieuwenhze, Michael S.
, p. 8536 - 8543 (2007/10/02)
Reactions of [(Z)-γ- [(diisopropylidene-α-D-mannopyranosyl)oxy]allyl]tributylstannane (6) with several chiral and achiral aldehydes are described. This reagent was designed in anticipation that significant diastereofacial bias in reactions with aldehydes
