1629050-67-4Relevant academic research and scientific papers
Repetitive two-step method for o,o,p- and o,p-oligophenylene synthesis through Pd-catalyzed cross-coupling of hydroxyterphenylboronic acid
Yamaguchi, Miyuki,Kimura, Takeshi,Shinohara, Naomi,Manabe, Kei
, p. 15207 - 15219 (2014/01/17)
A repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain lengths. X-ray crystallography was employed to obtain the structure of the o,p-oligophenylene 9-mer.
