163038-04-8Relevant articles and documents
Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts
Zuckerman, Dylan S.,Woerpel
, p. 4118 - 4129 (2019/06/24)
Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.
Revealing substrate promiscuity of 1-deoxy-D-xylulose 5-phosphate synthase
Brammer, Leighanne A.,Meyers, Caren Freel
supporting information; experimental part, p. 4748 - 4751 (2010/02/28)
A study of DXP synthase has revealed flexibility In the acceptor substrate binding pocket for nonpolar substrates and has uncovered new details of the catalytic mechanism to show that pyruvate can act as both donor and acceptor substrate.
Hydroxy-methyl-hexanones as flavoring agents
-
, (2008/06/13)
The present invention relates to new alpha -hydroxyketone compositions. In particular, there is provided 3-hydroxy-5-methyl-hexan-2-one, 2-hydroxy-5-methyl-hexan-3-one and mixtures thereof. These compounds have utility as flavoring and masking agents for, e.g., food and beverages. Processes for making such compounds also are provided.