163058-80-8

Basic information

• Product Name: (4S,5S)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde
• Synonyms: (4S,5S)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde
• CAS NO: 163058-80-8
• Molecular Weight: 250.295
• Mol File: 163058-80-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (4S,5S)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5S)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde(163058-80-8)
• EPA Substance Registry System: (4S,5S)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde(163058-80-8)

Safety Data

• Hazardous Substances Data: 163058-80-8(Hazardous Substances Data)

Upstream product

• 81076-11-1 (-)-1-O-Benzyl-2,3-O-isopropylideneerythritol 
• 130145-94-7 (2R,3S,4S,5S,6S,7S)-1,8-Bis-benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-octane-2,3,6,7-tetraol 
• 130146-05-3 C₃₄H₅₄O₄Si₂ 
• 162932-15-2 (2S,3R,4S,5S)-2,3-(propane-2,2-dioxy)hexane-1,4,5-triol 
• 264234-29-9 (3R,4S)-5-Benzyloxy-4-(2-methoxy-ethoxymethoxy)-pent-1-en-3-ol 
• 264234-28-8 (R)-2-[(S)-2-Benzyloxy-1-(2-methoxy-ethoxymethoxy)-ethyl]-oxirane 
• 210702-66-2 (2S,3R)-1-Benzyloxy-pent-4-ene-2,3-diol 
• 78469-89-3 (2S,3R)-1-benzyloxy-3,4-epoxy-2-butanol 
• 93553-66-3 1-(benzyloxy)but-3-en-2-ol 
• 2930-05-4 Benzyloxymethyl-oxiran 
• 210702-67-3 (4S,5R)-4-[(benzyloxy)methyl]-2,2-dimethyl-5-vinyl-1,3-dioxolane 
• 162932-16-3 1-O-benzyl-2,3-O-isopropylidene-L-rhamnitol 

Downstream Products

• 81028-17-3 (2R,3R)-3-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,3-dihydroxy-propionic acid methyl ester 
• 460718-32-5 (3S,6R,1'R,2'R,3'S)-3-[4-benzyloxy-1-hydroxy-2,3-isopropylidenedioxybutyl]-2,5-diethoxy-3,6-dihydro-6-isopropylpyrazine 
• 460718-36-9 (3R,6R,1'R,2'R,3'S)-3-[4-benzyloxy-1-hydroxy-2,3-isopropylidenedioxybutyl]-2,5-diethoxy-3,6-dihydro-6-isopropylpyrazine 
• 460718-34-7 (3S,6R,1'S,2'R,3'S)-3-[4-benzyloxy-1-hydroxy-2,3-isopropylidenedioxybutyl]-2,5-diethoxy-3,6-dihydro-6-isopropylpyrazine 
• 163058-81-9 5-O-Benzyl-1-desoxy-1,1,1-trifluoro-3,4-O-isopropylidene-L-arabinitol 
• 81076-11-1 (-)-1-O-Benzyl-2,3-O-isopropylideneerythritol 
• 128828-92-2 (E)-6-benzyloxy-1-<2-<1-<(4S,5R)-5-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-4-yl>-1-hydroxymethyl>-3-methoxyphenyl>-2-methoxy-1-hexene 
• 81028-16-2 (E)-3-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acrylic acid methyl ester 

Relevant articles and documents

Stereoselective synthesis of marine macrolide Aspergillide D

A formal stereoselective synthesis of the naturally occurring 16-membered macrolide aspergillide D is described. The origins of the chiral centers are ribose, lactic acid and the Sharpless asymmetric epoxidation protocol. The foremost reactions involved a

Homologation of allylic alcohols. An approach to cyclic and acyclic polyoxygenated compounds

The combination of the Sharpless asymmetric epoxidation reaction with a sulfur ylide mediated synthesis of allylic alcohols from epoxides provides a powerful iterative process for the production of polyoxygenated compounds. The alkene installed in the sulfur ylide reaction has also been used in a number of ring closing metathesis reactions to produce highly oxygenated cyclic compounds. (C) 2000 Elsevier Science Ltd.

High Diastereofacial Differentiation in Osmium Tetraoxide Catalyzed Dihydroxylation of Acyclic Bis-allylic Compounds

Bis-allylic compounds such as diethyl (4S,5S)-4,5-bis(tert-butyldimethylsilyl)oxy)-2,6-octadienedioate (1a) exhibit very high diastereoselection in osmiumtetraoxide catalyzed dihydroxylation; a particular ground-state conformation is proposed to be respon