163058-80-8

Upstream product

• 81076-11-1 (-)-1-O-Benzyl-2,3-O-isopropylideneerythritol 
• 130146-05-3 C₃₄H₅₄O₄Si₂ 
• 162932-15-2 (2S,3R,4S,5S)-2,3-(propane-2,2-dioxy)hexane-1,4,5-triol 
• 78469-89-3 (2S,3R)-1-benzyloxy-3,4-epoxy-2-butanol 
• 93553-66-3 1-(benzyloxy)but-3-en-2-ol 
• 2930-05-4 Benzyloxymethyl-oxiran 
• 210702-67-3 (4S,5R)-4-[(benzyloxy)methyl]-2,2-dimethyl-5-vinyl-1,3-dioxolane 
• 162932-16-3 1-O-benzyl-2,3-O-isopropylidene-L-rhamnitol 
• 264234-29-9 (3R,4S)-5-Benzyloxy-4-(2-methoxy-ethoxymethoxy)-pent-1-en-3-ol 
• 264234-28-8 (R)-2-[(S)-2-Benzyloxy-1-(2-methoxy-ethoxymethoxy)-ethyl]-oxirane 
• 210702-66-2 (2S,3R)-1-Benzyloxy-pent-4-ene-2,3-diol 
• 130145-94-7 (2R,3S,4S,5S,6S,7S)-1,8-Bis-benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-octane-2,3,6,7-tetraol 

Downstream Products

• 128828-92-2 (E)-6-benzyloxy-1-<2-<1-<(4S,5R)-5-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-4-yl>-1-hydroxymethyl>-3-methoxyphenyl>-2-methoxy-1-hexene 
• 81076-11-1 (-)-1-O-Benzyl-2,3-O-isopropylideneerythritol 
• 163058-81-9 5-O-Benzyl-1-desoxy-1,1,1-trifluoro-3,4-O-isopropylidene-L-arabinitol 
• 81028-17-3 (2R,3R)-3-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,3-dihydroxy-propionic acid methyl ester 
• 460718-32-5 (3S,6R,1'R,2'R,3'S)-3-[4-benzyloxy-1-hydroxy-2,3-isopropylidenedioxybutyl]-2,5-diethoxy-3,6-dihydro-6-isopropylpyrazine 
• 460718-36-9 (3R,6R,1'R,2'R,3'S)-3-[4-benzyloxy-1-hydroxy-2,3-isopropylidenedioxybutyl]-2,5-diethoxy-3,6-dihydro-6-isopropylpyrazine 
• 460718-34-7 (3S,6R,1'S,2'R,3'S)-3-[4-benzyloxy-1-hydroxy-2,3-isopropylidenedioxybutyl]-2,5-diethoxy-3,6-dihydro-6-isopropylpyrazine 
• 81028-16-2 (E)-3-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-acrylic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective synthesis of marine macrolide Aspergillide D

A formal stereoselective synthesis of the naturally occurring 16-membered macrolide aspergillide D is described. The origins of the chiral centers are ribose, lactic acid and the Sharpless asymmetric epoxidation protocol. The foremost reactions involved a

Substrate-controlled stereoselective synthesis of ophiocerin C

A novel stereoselective total synthesis of ophiocerin C was accomplished starting from l-(+)-tartaric acid. The C3,C4 vic-diol moiety was obtained from tartaric acid, and the stereogenic centre at C6 was created by substrate-controlled epoxidation and subsequent regioselective cleavage of the epoxide ring. Georg Thieme Verlag Stuttgart.

Homologation of allylic alcohols. An approach to cyclic and acyclic polyoxygenated compounds

The combination of the Sharpless asymmetric epoxidation reaction with a sulfur ylide mediated synthesis of allylic alcohols from epoxides provides a powerful iterative process for the production of polyoxygenated compounds. The alkene installed in the sulfur ylide reaction has also been used in a number of ring closing metathesis reactions to produce highly oxygenated cyclic compounds. (C) 2000 Elsevier Science Ltd.

Stereoselectivite comparee de la reduction de trifluoromethylcetones et des methylcetones correspondantes: nouvelles voies d'acces a des derives trifluoromethyles de pentoses

The selectivity of the reduction of some trifluoroacetyl-1,3-dioxanes and 1,3-dioxolanes with DIBAH or L-Selectride was studied and compared with that the corresponding methylketones; the results -in accordance with literature- show an important steric hi

High Diastereofacial Differentiation in Osmium Tetraoxide Catalyzed Dihydroxylation of Acyclic Bis-allylic Compounds

Bis-allylic compounds such as diethyl (4S,5S)-4,5-bis(tert-butyldimethylsilyl)oxy)-2,6-octadienedioate (1a) exhibit very high diastereoselection in osmiumtetraoxide catalyzed dihydroxylation; a particular ground-state conformation is proposed to be respon