16306-01-7

Basic information

• Product Name: 2-bromo-9-(4-methoxybenzyl)-9H-fluorene
• Synonyms: 2-bromo-9-(4-methoxybenzyl)-9H-fluorene
• CAS NO: 16306-01-7
• Molecular Weight: 365.269
• Mol File: 16306-01-7.mol

Chemical Properties

• CAS DataBase Reference: 2-bromo-9-(4-methoxybenzyl)-9H-fluorene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-9-(4-methoxybenzyl)-9H-fluorene(16306-01-7)
• EPA Substance Registry System: 2-bromo-9-(4-methoxybenzyl)-9H-fluorene(16306-01-7)

Safety Data

• Hazardous Substances Data: 16306-01-7(Hazardous Substances Data)

Upstream product

• 91805-38-8 (2-bromo-9H-fluoren-9-ylidene)hydrazine 
• 105-13-5 4-Methoxybenzyl alcohol 
• 1133-80-8 2-bromo-9H-fluorene 

Relevant articles and documents

Nickel-catalyzed synthesis of 9-monoalkylated fluorenes from 9-fluorenone hydrazone and alcohols

A practical protocol was disclosed for the nickel-catalyzed C-alkylation of 9-fluorenone hydrazone with alcohols using t-BuOK as the base, and 9-monoalkylated fluorene derivatives were obtained in good yields under the benign conditions.

T -BuOK-catalysed alkylation of fluorene with alcohols: A highly green route to 9-monoalkylfluorene derivatives

A simple, mild and efficient protocol was developed for the alkylation of fluorene with alcohols in the presence of t-BuOK as catalyst, affording the desired 9-monoalkylfluorenes with near quantitative yields in most cases.