163106-47-6Relevant articles and documents
Enantioselective synthesis of condensed and transannular ring skeletons containing pyrrolidine moiety
Mo, Fanyang,Li, Fei,Qiu, Di,Wang, Jianbo
experimental part, p. 1274 - 1279 (2010/03/30)
A new approach toward condensed and transannular ring structures containing pyrrolidine unit has been developed, based on diastereoselective nucleophilic addition of lithium enolate of α-diazoacetoacetate to chiral N-sulfinyl imine and ring-closing metathesis.
Novel route to fused nitrogen heterocycles by olefin metathesis
Martin, Stephen F.,Liao, Yusheng,Chen, Hui-Ju,Paetzel, Michael,Ramser, Melissa N.
, p. 6005 - 6008 (2007/10/02)
A novel technique for the efficient synthesis of fused nitrogen heterocycles has been developed that features the molybdenum alkylidene-catalyzed metathesis of α,ω-dienes containing a nitrogen atom in the chain linking the two olefinic functional groups. The starting materials may be readily prepared in three steps from succinimide and glutarimide via sequential Mitsunobu alkylation, sodium borohydride reduction, and addition of a vinyl cuprate to an N-acyliminium salt generated in situ.
