163213-87-4

Basic information

• Product Name: (+)-<3(S),4(S),S(R)>-tert-butyl 3-(2-methoxyethoxymethoxy)-4-(tert-butyldimethylsiloxy)-5-(p-tolylsulfinyl)pentanoate
• Synonyms: (+)-<3(S),4(S),S(R)>-tert-butyl 3-(2-methoxyethoxymethoxy)-4-(tert-butyldimethylsiloxy)-5-(p-tolylsulfinyl)pentanoate
• CAS NO: 163213-87-4
• Molecular Weight: 530.799
• Mol File: 163213-87-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-<3(S),4(S),S(R)>-tert-butyl 3-(2-methoxyethoxymethoxy)-4-(tert-butyldimethylsiloxy)-5-(p-tolylsulfinyl)pentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-<3(S),4(S),S(R)>-tert-butyl 3-(2-methoxyethoxymethoxy)-4-(tert-butyldimethylsiloxy)-5-(p-tolylsulfinyl)pentanoate(163213-87-4)
• EPA Substance Registry System: (+)-<3(S),4(S),S(R)>-tert-butyl 3-(2-methoxyethoxymethoxy)-4-(tert-butyldimethylsiloxy)-5-(p-tolylsulfinyl)pentanoate(163213-87-4)

Safety Data

• Hazardous Substances Data: 163213-87-4(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 163213-83-0 (+)-<3(S),4(S),S(R)>-tert-butyl 3-(2-methoxyethoxymethoxy)-4-hydroxy-5-(p-tolylsulfinyl)pentanoate 
• 163213-82-9 (+)-<3(S),S(R)>-tert-butyl 3-(2-methoxyethoxymethoxy)-4-oxo-5-(p-tolylsulfinyl)pentanoate 
• 163213-79-4 <3(S),S(R)> tert-butyl 3-(2-methoxyethoxymethoxy)-4-(p-tolylsulfinyl)butyrate 
• 163213-80-7 (+)3(S) tert-butyl 3-(2-methoxyethoxymethoxy)-4-acetoxybutyrate 
• 163213-81-8 (-)2(S)-methyl 2-(2-methoxyethoxymethoxy)-3-(tert-butoxycarbonyl)propanoate 
• 162971-44-0 (+) 3(S) tert-butyl 3-(2-methoxyethoxymethoxy)-4-hydroxybutyrate 
• 142176-68-9 (+)<3(S),S(R)> tert-butyl 3-hydroxy-4-(p-tolylsulfinyl)butyrate 
• 142176-64-5 (+)(R) tert-butyl 3-oxo-4-(p-tolylsulfinyl)butyrate 

Relevant articles and documents

Asymmetric synthesis induced by chiral sulfoxides : 2-deoxy-sugars from β-ketoesters via malic acid.

Keywords : β-keto-γ-alkoxysulfoxides, syn and anti-1,2-diols, β-ketosulfoxides reduction, 2-deoxy-D-ribose, 2-deoxy-L-xylose, malic acid. The asymmetric synthesis of (S)-malic esters was carried out by reduction of β-ketosulfoxides derived from β-ketoeste