1632147-71-7Relevant academic research and scientific papers
Synthesis of polysubstituted enynes through iron-catalyzed carbomagnesiation of conjugated diynes
Ilies, Laurean,Yoshida, Takumi,Nakamura, Eiichi
, p. 527 - 530 (2014)
Symmetrical and unsymmetrical conjugated diynes are chemo-, regio-, and stereoselectively carbomagnesiated with a ?Grignard reagent at room temperature in the presence of a catalytic amount of FeCl2 without the need for an external ligand. The resulting magnesium intermediate can be further functionalized to give polysubstituted 1,3-enyne derivatives. Georg Thieme Verlag Stuttgart New York.
