1632155-65-7

Basic information

• Product Name: methyl 3-methyl-2-(1H-pyrazol-1-yl)benzoate
• Synonyms: methyl 3-methyl-2-(1H-pyrazol-1-yl)benzoate
• CAS NO: 1632155-65-7
• Molecular Weight: 216.239
• Mol File: 1632155-65-7.mol

Chemical Properties

• CAS DataBase Reference: methyl 3-methyl-2-(1H-pyrazol-1-yl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-methyl-2-(1H-pyrazol-1-yl)benzoate(1632155-65-7)
• EPA Substance Registry System: methyl 3-methyl-2-(1H-pyrazol-1-yl)benzoate(1632155-65-7)

Safety Data

• Hazardous Substances Data: 1632155-65-7(Hazardous Substances Data)

Upstream product

• 1214622-58-8 3-methyl-2-(1H-pyrazol-1-yl)benzoic acid 
• 74-88-4 methyl iodide 
• 20157-44-2 1-o-tolyl-1H-pyrazole 
• 1632155-79-3 1-(2-methyl-6-triethylsilylphenyl)-1H-pyrazole 

Relevant articles and documents

Ruthenium-catalyzed c-h silylation of 1-arylpyrazole derivatives and fluoride-mediated carboxylation: Use of two nitrogen atoms of the pyrazole Group

Carboxylation of 1-arylpyrazole derivatives was developed using a ruthenium-catalyzed ortho silylation in conjunction with fluoride-mediated carboxylation with carbon dioxide. The two nitrogen atoms of pyrazole play crucial roles in promoting ortho silylation via the formation of a five-membered ruthenacycle and in accelerating aryl anion formation by lowering the electron density of the aromatic ring. Georg Thieme Verlag Stuttgart New York.