163228-38-4

Basic information

• Product Name: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE
• Synonyms: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE;6-O-(tert-butyldimethylsilyl)-D-galactal cyclic C;2,6-Anhydro-5-deoxy-1-O-[(1,1-dimethylethyl)dimethylsilyl]-D-arabino-hex-5-enitol cyclic carbonate;6-O-tert-Butyldimethylsilyl-3,4-O-carbonyl-D-galactal
• CAS NO: 163228-38-4
• Molecular Formula: C₁₃H₂₂O₅Si
• Molecular Weight: 320.41
• Mol File: 163228-38-4.mol
• Article Data: 3

Chemical Properties

• Melting Point: 45-49 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• CAS DataBase Reference: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE(163228-38-4)
• EPA Substance Registry System: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE(163228-38-4)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 163228-38-4(Hazardous Substances Data)

Upstream product

• 21193-75-9 D-galactal 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 530-62-1 1,1'-carbonyldiimidazole 
• 4098-06-0 triacetyl-D-galactal 
• 124751-19-5 (2R,3R,4R)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol 

Downstream Products

• 56248-18-1 methyl 2,3-dideoxy-4,6-di-O-benzoyl-β-D-threo-hex-2-enopyranoside 
• 188010-90-4 1,5-anhydro-6-O-benzyl-3,4-O-carbonate-2-deoxy-D-lyxo-hex-1-enopyranose 
• 149847-26-7 3,4-o-carbonyl-D-galactal 
• 167700-00-7 <(4-O-benzoyl-6-deoxy-2,3-di-O-benzyl-α-L-galactopyranosyl)-(1->3)-(6-O-(tert-butyldimethylsilyl)-β-D-galactopyranosyl)-(1->4)>-1,5-anhydro-6-O-(tert-butyldimethylsilyl)-2-deoxy-D-arabino-hex-1-enopyranose 

Relevant articles and documents

Selective Synthesis of Some Aminosugars via Catalytic Aminohydroxylation of Protected 2,3-Unsaturated d -Gluco- And d -Galacto-2-hexenopyranosides

The aminohydroxylation of methyl 4,6-di-O-(tert-butyldimethylsilyl)-2,3-unsaturated α-d-glucopyranoside proceeds in the presence of chloramine-T, OsO4 (4 mol %), (DHQ)2PHAL (5 mol %), and triethylbenzylammonium chloride (TEBAC) in both a stereoselective a

Application of glycals to the synthesis of oligosaccharides: Convergent total syntheses of the Lewis X trisaccharide sialyl Lewis X antigenic determinant and higher congeners

Exploiting the differences in reactivity of the hydroxyl groups of glucal allows for rapid access to the sLex tetrasaccharide glycal. This compound is readily converted to the title compounds by azaglycosylation followed by deprotection. The us