16358-73-9

Upstream product

• 22385-77-9 1-bromo-3,5-di-tert-butylbenzene 
• 14665-80-6 1,3-di-tert-butyl-5-isopropylbenzene 
• 365448-98-2 2-bromo-1,5-di-t-butyl-3-(1-cyanoethyl)benzene 
• 159556-96-4 2-bromo-1,5-di-t-butyl-3-(cyanomethyl)benzene 
• 365448-99-3 2-bromo-1,5-di-t-butyl-3-(1-formylethyl)benzene 

Downstream Products

• 365449-02-1 (2,4-di-t-butyl-6-isopropylphenyl)phosphonous dichloride 
• 862900-62-7 C₃₀H₃₆ClP 
• 1334501-55-1 N-(2-(3-(tert-butyl)-5-isopropylphenyl)-2-methylpropyl)aniline 
• 365449-03-2 (2,4-di-t-butyl-6-isopropylphenyl)phosphine 

Relevant academic research and scientific papers

Palladium(0)-catalyzed intermolecular amination of unactivated Csp 3-H bonds

Filling out the space: The title reaction of unactivated Csp3-H bonds using aryl amines as the nitrogen source is disclosed (see scheme; dba=dibenzylideneacetone, Tf=trifluoromethanesulfonyl). Either the C-N cross-coupling product or the C-H am

Preparation and 31P NMR study of some low-coordinated organophosphorus compounds bearing the 2,4-Di-t-butyl-6-isopropylphenyl group

2-Bromo-1,5-di-t-butyl-3-isopropyl-benzene was prepared and converted to the 2,4-di-t-butyl-6-isopropylphenyl-substituted phosphonous di-chloride, primary phosphine, diphosphenes, and dithioxophosphorane. The 31P NMR chemical shifts of these compounds are close to those of 2,4-di-t-butyl-6-methylphenyl substituted congeners.