163592-77-6Relevant academic research and scientific papers
Synthesis of Sugar Episulfides and Olefins from vic-Diols via Cyclic Sulfates
Santoyo-Gonzalez, Francisco,Garcia-Calvo-Flores, Francisco,Garcia-Mendoza, Pilar,Hernandez-Mateo, Fernando,Isac-Garcia, Joaquin,Perez-Alvarez, M. Dolores
, p. 461 - 462 (1995)
Cyclic sulfates of vic-diols are transformed in one-pot into sugar episulfides by treatment with potassium thioacetate or thiourea followed by reaction with sodium methoxide; reaction of these cyclic sulfates with potassium selenocyanate followed by treat
Applications of Cyclic Sulfates of vic-Diols: Synthesis of Episulfides, Olefins, and Thio Sugars
Calvo-Flores, Francisco G.,Garcia-Mendoza, Pilar,Hernandez-Mateo, Fernando,Isac-Garcia, Joaquin,Santoyo-Gonzalez, Francisco
, p. 3944 - 3961 (2007/10/03)
A new efficient and expeditious one-pot synthesis of thiiranes and olefins from cyclic sulfates of inc-diols is described. Opening of cyclic sulfates with potassium thioacetate or potassium thiocyanate followed by treatment with sodium methoxide led to ep
