163628-20-4

Basic information

• Product Name: 5-(1,10-Phenanthroline-5-ylaMino)-5-oxopentanoic acid
• Synonyms: 5-(1,10-Phenanthroline-5-ylaMino)-5-oxopentanoic acid;5-((1,10-Phenanthrolin-5-yl)amino)-5-oxopentanoic acid
• CAS NO: 163628-20-4
• Molecular Formula: C17H15N3O3
• Molecular Weight: 309.3193
• Mol File: 163628-20-4.mol
• Article Data: 1

Chemical Properties

• Melting Point: 233-235 °C(Solv: chloroform (67-66-3))
• Boiling Point: 676.6±45.0 °C(Predicted)
• Appearance: /
• Density: 1.397±0.06 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• PKA: 4.70±0.10(Predicted)
• CAS DataBase Reference: 5-(1,10-Phenanthroline-5-ylaMino)-5-oxopentanoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(1,10-Phenanthroline-5-ylaMino)-5-oxopentanoic acid(163628-20-4)
• EPA Substance Registry System: 5-(1,10-Phenanthroline-5-ylaMino)-5-oxopentanoic acid(163628-20-4)

Safety Data

• Hazardous Substances Data: 163628-20-4(Hazardous Substances Data)

Upstream product

• 108-55-4 glutaric anhydride, 
• 54258-41-2 1,10-phenanthroline-5-amine 

Relevant articles and documents

Synthesis and characterisation of N-1,10-phenanthrolin-5-ylalkylamides and their photosensitising heteroleptic Ru(II) complexes

In the context of our studies on ruthenium(II) complexes containing polyazaheterocyclic ligands as functionalised photosensitisers for singlet molecular oxygen generation in heterogeneous phase, we describe the synthesis and spectroscopic characterisation of different amide-functionalised N-1,10-phenanthrolin-5-ylalkylamides. These chelators are used to obtain heteroleptic [Ru(phen)2L2+ complexes, where L stands for 2-iodo-N-1,10-phenanthrolin-5-ylacetamide (5-iap), 4-oxo-4-(1,10-phenanthrolin- 5-ylamino)butanoic acid (5-suap), 5-oxo-5-(1,10-phenanthrolin-5-ylamino) pentanoic acid (5-glap) and tert-butyl 4-oxo-4-(1,10-phenanthrolin-5-ylamino) butylcarbamate (BOC-5-ngap). The spectroscopic data, excited state lifetimes and quenching rate constants with O2 (ca. 3.7 × 109 L mol-1 s-1) of these novel complexes are also reported.