163686-46-2Relevant academic research and scientific papers
Generation, reactions, and kinetics of sterically congested triplet diphenylcarbenes. Effects of bromine groups
Tomioka, Hideo,Watanabe, Tetsuya,Hattori, Makoto,Nomura, Naoki,Hirai, Katsuyuki
, p. 474 - 482 (2007/10/03)
A series of polybrominated diphenylcarbenes (DPCs) are generated by irradiation of the corresponding precursor diazomethanes, and their reactivities are investigated by means of low-temperature spectroscopies as well as laser flash photolysis. Triplet bis
Electronic and molecular structures of room-temperature stable triplet carbene as studied by ESR and x-ray crystal analysis of the diazo precursor
Takui,Furukawa,Itoh,Miyahara,Hirotsu,Watanabe,Hirai,Tomioka
, p. 247 - 252 (2007/10/03)
We report the first room-temperature stable triplet π-aryl based carbene, 2,2′,4,4′,6,6′,-hexabromodiphenylmethylene 2 in both crystals and fluid solutions. This paper describes ESR detection of 2 in the crystal of the diazo precursor 1 and the molecular
