163705-84-8Relevant articles and documents
An improved synthesis of enantiopure β-amino acids
Cimarelli,Palmieri,Volpini
, p. 2943 - 2953 (2001)
An improved method for the preparation of both the enantiopure β-amino acids is presented. The diastereomer benzyl β-amino esters, obtained by stereoselective reduction of β-enamino esters, were separated and hydrogenolyzed to the free enantiopure β-amino acids.
Diastereo and Enantioselective Entry to β-Amino Esters by Hydride Reduction of Homochiral β-Enamino Esters.
Cimarelli, Cristina,Palmieri, Gianni,Bartoli, Giuseppe
, p. 1455 - 1458 (2007/10/02)
The reduction of homochiral β-enamino esters 1 with sodium triacetoxyborohydride, which occurs with good diastereo- and enantioselectivity in the β-amino esters 2, is described.The procedure allows a straightforward preparation of compounds with known bio