1638114-50-7

Basic information

• Product Name: C₂₆H₂₂N₄
• Synonyms: C₂₆H₂₂N₄
• CAS NO: 1638114-50-7
• Molecular Weight: 390.487
• Mol File: 1638114-50-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₆H₂₂N₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₂₂N₄(1638114-50-7)
• EPA Substance Registry System: C₂₆H₂₂N₄(1638114-50-7)

Safety Data

• Hazardous Substances Data: 1638114-50-7(Hazardous Substances Data)

Upstream product

• 3731-51-9 2-(Aminomethyl)pyridine 
• 1210-05-5 Biphenyl-2,2'-dicarbaldehyde 

Relevant articles and documents

A biomimetic catalytic aerobic functionalization of phenols

The importance of aromatic C-O, C-N, and C-S bonds necessitates increasingly efficient strategies for their formation. Herein, we report a biomimetic approach that converts phenolic C-H bonds into C-O, C-N, and C-S bonds at the sole expense of reducing dioxygen (O2) to water (H 2O). Our method hinges on a regio- and chemoselective copper-catalyzed aerobic oxygenation to provide ortho-quinones. ortho-Quinones are versatile intermediates, whose direct catalytic aerobic synthesis from phenols enables a mild and efficient means of synthesizing polyfunctional aromatic rings. The direct approach: Polyfunctional aromatic rings have been generated by direct functionalization of C-H bonds to C-O, C-N, and C-S bonds at the sole expense of reducing O2 to H2O. The method hinges on a regio- and chemoselective, copper-catalyzed aerobic oxygenation of phenols to provide ortho-quinones (see scheme), thus mimicking the ubiquitous biosynthetic pathway of melanogenesis.