1638606-74-2

Basic information

• Product Name: C₁₂H₉F
• Synonyms: C₁₂H₉F
• CAS NO: 1638606-74-2
• Molecular Weight: 172.202
• Mol File: 1638606-74-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₂H₉F(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₉F(1638606-74-2)
• EPA Substance Registry System: C₁₂H₉F(1638606-74-2)

Safety Data

• Hazardous Substances Data: 1638606-74-2(Hazardous Substances Data)

Upstream product

• 137338-08-0 C₉H₅FO 
• 3607-17-8 3-bromopropyltriphenylphosphonium bromide 

Downstream Products

• 1638606-37-7 C₁₉H₁₆FN₃O₂S 

Relevant articles and documents

Rhodium(II)-catalyzed intramolecular cycloisomerizations of methylenecyclopropanes with N-Sulfonyl 1,2,3-Triazoles

A novel rhodium(II)-catalyzed tandem cycloisomerization of methylenecyclopropanes (MCPs) with N-sulfonyl 1,2,3-triazoles is disclosed. The reaction produces a series of highly functionalized polycyclic Nheterocycles via a rhodium imino carbene intermediate. A distinct feature of this divergent synthesis is that different types of substrates control the reaction pathways. Moreover, several interesting transformations of these products to construct diazabicyclo[3.2.1]octane derivatives are also reported. The azavinyl rhodium carbenes derived from N-sulfonyltriazole methylenecyclopropanes were found to be very reactive in the divergent synthesis of N-containing heterocycles. Different types of cycloisomerizations were observed depending on the substrates. Derivatization of the products easily gave a series of diazabicyclo[3.2.1]octane derivatives. Bs=bromobenzenesulfonyl, Ms=methanesulfonyl, Piv=pivalate, Ts=4-toluenesulfonyl.