1638754-99-0

Upstream product

• 24599-57-3 1,3-cyclohexadiene monoxide 
• 100-58-3 phenylmagnesium bromide 
• 108-86-1 bromobenzene 
• 913192-84-4 phenyl[2-[(trimethylsilanyl)ethynyl]phenyl]methanol 
• 77123-58-1 2-[2-(trimethylsilyl)ethynyl]benzaldehyde 

Downstream Products

• 1638755-15-3 N-benzyl-N-((2-(methoxy(phenyl)methyl)phenyl)ethynyl)methanesulfonamide 
• 1638755-16-4 N-((2-(methoxy(phenyl)methyl)phenyl)ethynyl)-N-methylmethanesulfonamide 
• 1638755-17-5 N-((2-(methoxy(phenyl)methyl)phenyl)ethynyl)-N-methyl-4-nitrobenzenesulfonamide 
• 1638755-19-7 N-allyl-N-((2-(methoxy(phenyl)methyl)phenyl)ethynyl)methanesulfonamide 
• 1638755-60-8 N-(3-methoxy-1-phenyl-1H-inden-2-yl)-N-methyl-4-nitrobenzenesulfonamide 
• 1638755-61-9 N-allyl-N-(3-methoxy-1-phenyl-1H-inden-2-yl)methanesulfonamide 
• 1638755-20-0 3-((2-(methoxy(phenyl)methyl)phenyl)ethynyl)oxazolidin-2-one 
• 1638755-22-2 (4S)-4-benzyl-3-((2-(methoxy(phenyl)methyl)phenyl)ethynyl)oxazolidin-2-one 

Relevant academic research and scientific papers

Divergent C-H Insertion-Cyclization Cascades of N-Allyl Ynamides

Gold carbene reactivity patterns were accessed by ynamide insertion into a C(sp3)-H bond. A substantial increase in molecular complexity occurred through the cascade polycyclization of N-allyl ynamides to form fused nitrogen-heterocycle scaffol

1,2-N-migration in a gold-catalysed synthesis of functionalised indenes by the 1,1-carboalkoxylation of ynamides

Unique α-hemiaminal ether gold carbene intermediates were accessed by a gold-catalysed 1,1-carboalkoxylation strategy and evolved through a highly selective 1,2-N-migration. This skeletal rearrangement gave functionalised indenes, and isotopic labelling c