163886-16-6

Basic information

• Product Name: METHYL BROMOACETATE-2,2-D2
• Synonyms: METHYL BROMOACETATE-2,2-D2;METHYL BROMOACETATE-D2;METHYL BROMOACETATE-D2, 98 ATOM % D
• CAS NO: 163886-16-6
• Molecular Formula: C₃H₅BrO₂
• Molecular Weight: 154.99
• Product Categories: Alphabetical Listings;M;Stable Isotopes
• Mol File: 163886-16-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 51-52 °C15 mm Hg(lit.)
• Flash Point: 145 °F
• Appearance: /
• Density: 1.637 g/mL at 25 °C(lit.)
• Vapor Pressure: 3.25mmHg at 25°C
• Refractive Index: n20/D 1.458(lit.)
• CAS DataBase Reference: METHYL BROMOACETATE-2,2-D2(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL BROMOACETATE-2,2-D2(163886-16-6)
• EPA Substance Registry System: METHYL BROMOACETATE-2,2-D2(163886-16-6)

Safety Data

• Hazard Codes: C,T
• Statements: 34-36/37-37-25
• Safety Statements: 23-26-27-36/37/39-45
• RIDADR: UN 2643 6.1/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 163886-16-6(Hazardous Substances Data)

Usage

Uses

Methyl Bromoacetate-2,2-d2 (CAS# 163886-16-6) is a useful isotopically labeled research compound.

InChI:InChI=1/C3H5BrO2/c1-6-3(5)2-4/h2H2,1H3/i2D2

Upstream product

• 67-56-1 methanol 
• 1186-52-3 tetradeuterioacetic acid 
• 1112-02-3 d⁽³⁾-acetic acid 
• 67-68-5 dimethyl sulfoxide 

Downstream Products

• 1066775-01-6 4-(2-iodobenzyl)-3,3-dideuteromorpholin-2-one 
• 1779-57-3 (Triphenylphosphonio)-(methoxycarbonyl)dideuteriomethanbromide 

Relevant articles and documents

On the reported intermediacy of vinyl radicals in spontaneous polymerization: An ESR-spin trapping study and its significance for the bond forming initiation theory

Deuterated isopropyl vinyl sulfides and diethyl fumarate were synthesized and employed in a re-investigation of the mechanism of initiation of spontaneous polymerization of these comonomers by means of spin- trapping/ESR spectroscopy. Previous radical spin-trapping studies had been interpreted as indicating the involvement of vinyl radicals. While our studies produced data substantially in agreement with the previous study, it must be noted that the date are not consistent with literature data for other vinyl radicals. Accordingly, results from both spin-trapping/ESR studies me inconsistent with involvement of vinyl radical intermediates, but are consistent with initiation by tetramethylene diradicals.