1639453-20-5Relevant articles and documents
Synthesis, characterization, and reactivity of novel 6H-1,3,5-oxathiazine S,S-dioxides
Islam, Md. Rafiqul,Takikawa, Yuji,Lim, Kwon Taek
, p. 604 - 609 (2014)
A series of novel 6H-1,3,5-oxathiazine S,S-dioxides were synthesized by the m-CPBA oxidation (2.2 equiv) of 6H-1,3,5-oxathizines. The synthetic utilities of the newly synthesized cyclic sulfones were investigated. In a thermal condition, compounds 6H-1,3,5-oxathiazine S,S-dioxides were found relatively stable, but Lewis acid-induced thermal reaction afforded the corresponding amides. The plausible pathway to amides from 6H-1,3,5-oxathiazine S,S-dioxides was also discussed in this account.