16395-18-9Relevant academic research and scientific papers
QUANTITATIVE DESCRIPTION OF REACTIONS OF AROMATIC COMPOUNDS WITH ELECTROPHILIC AGENTS. I. ELECTROPHILIC HYDROXYLATION OF METHYLBENZENES
Koptyug, V. A.,Rogozhnikova, O. Yu.,Detsina, A. N.
, p. 1193 - 1203 (2007/10/02)
A scheme is proposed by means of which it is possible to assess the role of various reaction paths and the composition of the reaction products in terms of the theory of electrophilic hydroxylation of methylbenzenes by the initial addition of the electrophile at a ring carbon-carbon ? bond, controlled by charge and orbital factors, and the subsequent formation of isomeric ? complexes in ratios determined by their thermodynamic stability.
Tricyclic alcohols
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, (2008/06/13)
Tricyclic alcohol compounds having the formula: STR1 wherein each of R1, R2, R3, R4, R5 and R6 is selected from the group consisting of hydrogen and methyl; wherein the dashed line is a carbon-carbon single bond or a carbon-carbon double bond; and wherein, when the dashed line is a carbon-carbon single bond, one of R2 or R3 is hydrogen; useful in preparing compositions for augmenting or enhancing the flavor and/or aroma of consumble products including foods, tobacco and perfumes.
