16396-62-6

Basic information

• Product Name: Boroxin, tris(4-ethenylphenyl)-
• CAS NO: 16396-62-6
• Molecular Formula: C24H21B3O3
• Molecular Weight: 389.862
• Mol File: 16396-62-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Boroxin, tris(4-ethenylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Boroxin, tris(4-ethenylphenyl)-(16396-62-6)
• EPA Substance Registry System: Boroxin, tris(4-ethenylphenyl)-(16396-62-6)

Safety Data

• Hazardous Substances Data: 16396-62-6(Hazardous Substances Data)

Upstream product

• 22873-28-5 p-ethylphenylmagnesium bromide 
• 91113-72-3 tris(2-ethyl phenyl) boroxine 
• 21450-63-5 2-ethylphenylmagnesium bromide 
• 688-74-4 boric acid tributyl ester 
• 7442-12-8 poly(4-vinylphenyllithium) 
• 7459-73-6 (4-Vinylphenyl)magnesium chloride 
• 91113-71-2 tris(4-ethyl phenyl) boroxine 
• 124112-23-8 {B(C₆H₄-4-CHBrCH₃)O}3 
• 1073-67-2 4-vinylbenzyl chloride 
• 2156-04-9 4-Vinylphenylboronic acid 

Downstream Products

• 870004-04-9 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styrene 
• 3435-51-6 4-ethenylbenzonitrile 
• 1613507-15-5 (S,E)-1-(4-phenylbut-3-en-2-yl)-4-vinylbenzene 

Relevant articles and documents

Selective Recognition of d -Aldohexoses in Water by Boronic Acid-Functionalized, Molecularly Imprinted Cross-Linked Micelles

Molecular imprinting within cross-linked micelles using 4-vinylphenylboronate derivatives of carbohydrates provided water-soluble nanoparticle receptors selective for the carbohydrate templates. Complete differentiation of d-aldohexoses could be achieved

Copper-mediated anomeric: O -arylation with organoboron reagents

Copper-mediated couplings of arylboroxines with glycosyl hemiacetals furnish O-aryl glycosides via Csp2-O bond formation. The method enables the anomeric O-arylation of protected pyranose and furanose derivatives, and is tolerant of functionalized arylboroxine partners. Whereas mixtures of anomers are formed from glucopyranose, galactopyranose and arabinofuranose hemiacetals, the α-anomer is generated selectively from mannopyranose and mannofuranose-derived substrates.

Copper-Catalyzed Cyanation of Aryl- and Alkenylboronic Reagents with Cyanogen Iodide

Direct catalytic cyanation of organoboronic acids with cyanogen iodide has been achieved by using a copper-bipyridine catalyst system. The cyanation reaction is likely to occur through two catalytic cycles: copper(II)-catalyzed iodination of organoboronic acids and the following cyanidocopper(I)-mediated cyanation of organic iodides.