16396-62-6

Upstream product

• 2156-04-9 4-Vinylphenylboronic acid 
• 1073-67-2 4-vinylbenzyl chloride 
• 124112-23-8 {B(C₆H₄-4-CHBrCH₃)O}3 
• 91113-71-2 tris(4-ethyl phenyl) boroxine 
• 7459-73-6 (4-Vinylphenyl)magnesium chloride 
• 688-74-4 boric acid tributyl ester 
• 7442-12-8 poly(4-vinylphenyllithium) 
• 21450-63-5 2-ethylphenylmagnesium bromide 
• 91113-72-3 tris(2-ethyl phenyl) boroxine 
• 22873-28-5 p-ethylphenylmagnesium bromide 

Downstream Products

• 51636-02-3 (R)-2-(4-vinyl-phenyl)-[1,3,2]dioxaborolane-4-carboxylic acid 4-vinyl-anilide 
• 55032-23-0 (R)-2-(4-vinyl-phenyl)-[1,3,2]dioxaborolane-4-carboxylic acid 4-vinyl-phenethylamide 
• 55057-99-3 2-(4-vinyl-phenyl)-[1,3,2]dioxaborolane-4-carboxylic acid 4-vinyl-anilide 
• 870004-04-9 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styrene 
• 1613507-15-5 (S,E)-1-(4-phenylbut-3-en-2-yl)-4-vinylbenzene 
• 3435-51-6 4-ethenylbenzonitrile 

Relevant academic research and scientific papers

Selective Recognition of d -Aldohexoses in Water by Boronic Acid-Functionalized, Molecularly Imprinted Cross-Linked Micelles

Molecular imprinting within cross-linked micelles using 4-vinylphenylboronate derivatives of carbohydrates provided water-soluble nanoparticle receptors selective for the carbohydrate templates. Complete differentiation of d-aldohexoses could be achieved

Preparation of organoboron block copolymers via ATRP of silicon and boron-functionalized monomers

The organoboron block copolymers were fabricated by atom transfer radical polymerization (ATRP) of silicon and boron-functionalized monomer, MBpin. It was observed that the reactivity of the functionalized monomer was similar to that of styrene, though MB

Copper-mediated anomeric: O -arylation with organoboron reagents

Copper-mediated couplings of arylboroxines with glycosyl hemiacetals furnish O-aryl glycosides via Csp2-O bond formation. The method enables the anomeric O-arylation of protected pyranose and furanose derivatives, and is tolerant of functionalized arylboroxine partners. Whereas mixtures of anomers are formed from glucopyranose, galactopyranose and arabinofuranose hemiacetals, the α-anomer is generated selectively from mannopyranose and mannofuranose-derived substrates.

Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acids

By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metal-free carbon-carbon homologation of aryl and vinyl boroxines using TMSCHN2, giving access to TMS-pinacol boronic ester products, was developed.

Copper-Catalyzed Cyanation of Aryl- and Alkenylboronic Reagents with Cyanogen Iodide

Direct catalytic cyanation of organoboronic acids with cyanogen iodide has been achieved by using a copper-bipyridine catalyst system. The cyanation reaction is likely to occur through two catalytic cycles: copper(II)-catalyzed iodination of organoboronic acids and the following cyanidocopper(I)-mediated cyanation of organic iodides.

Diastereoselective synthesis of vicinally bis(trifluoromethylated) alkylboron compounds through successive insertions of 2,2,2-trifluorodiazoethane

The usefulness of embedded CF3 substituents within organic substructures necessitates the development of diverse methods for incorporating this functional group. A recently reported route to α-trifluoromethylated alkylboron compounds by an α-transfer mechanism has now been extended to the synthesis of unprecedented, vicinally ditrifluoromethylated alkylboron compounds in a diastereoselective fashion. The utility of these products is highlighted by conversion of the C-B bond into other functional groups.