163979-90-6Relevant academic research and scientific papers
A convenient synthesis of unsymmetrical N,N'disubstituted α,ω- diaminoalkanes
Orelli, Liliana R.,Salerno, Alejandra,Hedrera, Monica E.,Perillo, Isabel A.
, p. 1625 - 1639 (1998)
A general procedure is described for regiospecific construction of unsymmetrical N-alkyl (or aralkyl)-N'-aryl-α,ω-diaminoalkanes 3 (n=2,3,4) by reduction of N-(ω -arylaminoalkyl)amides 2 with borane. Compounds 2 are readily obtained by condensation of N-(
1H-4,5,6,7-tetrahydro-1,3-diazepines. Part II: Basicity and hydrolysis of 1,2-diaryl derivatives
Hedrera,Perillo,Fernandez
, p. 895 - 900 (2007/10/03)
Basicity and alkaline hydrolysis of 1,2-diaryl-1h -4,5,6,7-tetrahydro-1,3-diazepines 1 are studied. Results are analyzed on the basis of Hammett and Swain-lupton constants, finding good structure-basicity correlation when both, inductive and mesomeric eff
