Welcome to LookChem.com Sign In|Join Free

CAS

  • or

16409-46-4

Post Buying Request

16409-46-4 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

16409-46-4 Usage

Description

Menthyl isovalerate has an odor similar to both menthol and isovaleric acid, sweet and herbaceous, somewhat balsamic or root-like. It has a bitter, wood-like taste. Prepared by heating a mixture of ι-menthol and isovaleric acid at 100 - 110°C in the presence of trace concentrated H2SO4 or at 100°C in the presence of HCL.

Chemical Properties

Menthyl isovalerate has an odor similar to both menthol and isovaleric acid, sweet and herbaceous. It has a bitter, wood like taste.

Occurrence

Reported found in several peppermint essential oils: American, French, English, and Russian peppermint and nutmeg

Preparation

Prepared by heating a mixture of l-menthol and isovaleric acid at 100 to 110°C in the presence of trace concentrated H2SO4 or at 100°C in the presence of HCl.

Taste threshold values

Taste characteristics at 80 ppm: fruity, sweet, with a tutti-fruitti background.

Hazard

Low toxicity by ingestion and skin contact. A moderate skin contact irritant.

Check Digit Verification of cas no

The CAS Registry Mumber 16409-46-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,4,0 and 9 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 16409-46:
(7*1)+(6*6)+(5*4)+(4*0)+(3*9)+(2*4)+(1*6)=104
104 % 10 = 4
So 16409-46-4 is a valid CAS Registry Number.
InChI:InChI=1/C15H28O2/c1-10(2)8-15(16)17-14-9-12(5)6-7-13(14)11(3)4/h10-14H,6-9H2,1-5H3

16409-46-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Menthyl isovalerate

1.2 Other means of identification

Product number -
Other names Menthylisovalerat

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16409-46-4 SDS

16409-46-4Synthetic route

carbon monoxide
201230-82-2

carbon monoxide

menthol
89-78-1

menthol

isobutene
115-11-7

isobutene

menthyl isovalerate
16409-46-4

menthyl isovalerate

Conditions
ConditionsYield
With palladium diacetate; hydrogen; toluene-4-sulfonic acid; triphenylphosphine In xylene at 100℃; under 13680 Torr; for 2h;99.7%
With hydrogen; bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane; xylene at 130℃; under 33440 Torr; for 21h; Product distribution; var. reactions conditions;62%
With hydrogen; bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane; xylene at 130℃; under 33440 Torr; for 21h;62%
With palladium diacetate; hydrogen; toluene-4-sulfonic acid; triphenylphosphine In xylene at 100℃; under 13680 Torr; for 2h; other rate of hydrocarboxylation, var. component ratio, var. solvents;
3-methylbutyric acid
503-74-2

3-methylbutyric acid

(-)-menthol
2216-51-5

(-)-menthol

menthyl isovalerate
16409-46-4

menthyl isovalerate

Conditions
ConditionsYield
With sulfuric acid at 100 - 110℃; -isovalerate;
With mineral acid at 70 - 80℃; isovaleric acid l-menthyl ester;
(-)-menthol
2216-51-5

(-)-menthol

isopentanoyl chloride
108-12-3

isopentanoyl chloride

menthyl isovalerate
16409-46-4

menthyl isovalerate

Conditions
ConditionsYield
With pyridine; benzene isovaleric acid l-menthyl ester;

16409-46-4Downstream Products

16409-46-4Relevant articles and documents

PREPARATION OF MENTHYL ISOVALERATE BY CARBONYLATION OF ISOBUTYLENE

El'man, A. R.,Matveev, V. M.,Slivinskii, E. V.,Loktev, S. M.

, p. 217 - 221 (1990)

-

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 16409-46-4