16419-78-6Relevant articles and documents
Brockman
, p. 507,508 (1955)
Photochemistry of cyanoacetylene at 193.3 nm
Seki, Kanekazu,He, Maoqi,Liu, Renzhang,Okabe, Hideo
, p. 5349 - 5353 (2007/10/03)
Cyanoacetylene (CA) is an important minor constituent in the Titan atmosphere and is present in the interstellar medium. The absorption cross section of CA has been measured in the region from 190 to 255 nm with a resolution of 1 nm. The photochemistry of CA at 193.3 nm has been studied using a quadrupole mass spectrometer and a Fourier transform infrared spectrometer for product analysis. From the photolysis of HC3N-D2 and HC3N-CD4 mixtures and a plateau value of 0.3 for the quantum yield (QY) of DC3N (C3N + D2 → DC3N + D), it is concluded that the main dissociation process is HC3N + hv → H + C3N with a QY of 0.30 ± 0.05 and a minor process is HC3N + hv → C2H + CN with a QY equal to or less than 0.02. The remaining process is the formation of metastable CA (a triplet or carbene). The photolysis of CA induces a noticeable pressure decrease and a concomitant formation of a mist. The QY of CA disappearance is 4.5 ± 0.5, which is much higher than that of diacetylene (QY = 2.0 ± 0.5) and of acetylene (QY = 2.3). The rapid mist formation in CA may explain a haze observed in the Titan atmosphere. A detailed mist formation process is not known. The C3N radical disappears partially by C3N + HC3N → C6N2 + H and 2C3N → C6N2. To explain the formation of minor products, HCN, C2H2, HC5N, and C4N2, two processes involving an unspecified CA metastable state or states may be proposed: HC3N* + HC3N → HC5N + HCN and C4N2 + C2H2.
